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Peptide bonds to proline, and to other N-substituted amino acids (equivalent to sarcosine), are able to populate both the cis and trans isomers. Such interactions can only occur if the oxygen-containing peptide bond has a trans configuration. We observed that the interconversion across the peptide bond for l-alanyl-l-proline (Ala-Pro) in water is accelerated at the […]

As most nutrient supplements feed all dwelling microorganism in the must (whether fascinating or not), winemakers will typically wait to add the nutrients until they are ready to inoculate the must with their desired S. cerevisiae pressure. Specifically, four proline 4-hydroxylases (P4H) were chosen to convert l-proline to Hyp, and the recombinant strain overexpressing DsP4H […]

1. Pokorný V., ?ervinka C., Štejfa V., Havlín J., R?ži?ka K., Fulem M. Heat Capacities of L-Alanine, L-Valine, L-Isoleucine, and L-Leucine: Experimental and Computational Study. R?ži?ka K, Štejfa V, ?ervinka C, Fulem M, Šturala J. R?ži?ka K, et al. Pokorný V, Štejfa V, Havlín J, Fulem M, R?ži?ka K. Pokorný V, et al. Štejfa V, […]

However, the first step in phospholipid synthesis entails the formation of phosphatidate or diacylglycerol 3-phosphate on the endoplasmic reticulum and outer mitochondrial membrane. Anionic cyclization of o-alkynylbenzamides is proposed as a vital step in many heterocycle syntheses. The cyclization can produce three merchandise: Z-3-methylenisoindolin-1-one (Z-5-exo), E-3-methylenisoindolin-1-one (E-5-exo), and isoquinolinone (6-endo). Under base catalysis, the selectivity […]

McNamara PD, Pepe LM, Segal S. McNamara PD, et al. Foreman JW, McNamara PD, Pepe LM, Ginkinger K, Segal S. Foreman JW, et al. Hsu BY, Foreman JW, Corcoran SM, Ginkinger K, Segal S. Hsu BY, et al. Foreman JW, Reynolds RA, Ginkinger K, Segal S. Foreman JW, et al. Goldmann DR, Roth KS, Langfitt […]